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| 04.09.1966 | 15:30 | Borussia Neunkirchen | - | FC 08 Homburg | 1:1 | |
| 15:30 | SV Weisenau | - | 1. FSV Mainz 05 | 1:1 | ||
| 15:30 | Eintracht Trier | - | 1. FC Saarbrücken | 2:1 | ||
| 15:30 | SV Südwest Ludwigshafen | - | Phönix Bellheim | 3:1 | ||
| 15:30 | SV Röchling Völklingen | - | Wormatia Worms | 1:1 | ||
| 15:30 | VfR Frankenthal | - | Saar 05 Saarbrücken | 4:4 | ||
| 15:30 | TuS Neuendorf | - | SV Alsenborn | 2:3 | ||
| 15:30 | Germania Metternich | - | FK Pirmasens | 0:1 |
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
1. FSV Mainz 05 | 5 | 4 | 1 | 0 | 11:3 | 8 | 9:1 |
| 2 |
|
Borussia Neunkirchen | 5 | 3 | 2 | 0 | 18:4 | 14 | 8:2 |
| 3 |
|
1. FC Saarbrücken | 5 | 4 | 0 | 1 | 14:3 | 11 | 8:2 |
| 4 |
|
Saar 05 Saarbrücken | 5 | 3 | 2 | 0 | 11:6 | 5 | 8:2 |
| 5 |
|
FK Pirmasens | 5 | 3 | 1 | 1 | 13:5 | 8 | 7:3 |
| 6 |
|
VfR Frankenthal | 5 | 2 | 2 | 1 | 11:7 | 4 | 6:4 |
| 7 |
|
Eintracht Trier | 5 | 2 | 1 | 2 | 8:9 | -1 | 5:5 |
| 8 |
|
SV Weisenau | 5 | 2 | 1 | 2 | 8:10 | -2 | 5:5 |
| 9 |
|
SV Südwest Ludwigshafen | 5 | 2 | 0 | 3 | 10:11 | -1 | 4:6 |
| 10 |
|
Wormatia Worms | 5 | 1 | 2 | 2 | 8:10 | -2 | 4:6 |
| 11 |
|
SV Alsenborn | 5 | 2 | 0 | 3 | 9:12 | -3 | 4:6 |
| 12 |
|
Phönix Bellheim | 5 | 1 | 1 | 3 | 7:13 | -6 | 3:7 |
| 13 |
|
SV Röchling Völklingen | 5 | 1 | 1 | 3 | 3:9 | -6 | 3:7 |
| 14 |
|
FC 08 Homburg | 5 | 0 | 3 | 2 | 4:13 | -9 | 3:7 |
| 15 |
|
TuS Neuendorf | 5 | 1 | 0 | 4 | 5:16 | -11 | 2:8 |
| 16 |
|
Germania Metternich | 5 | 0 | 1 | 4 | 1:10 | -9 | 1:9 |
