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| 11.09.1966 | 15:30 | 1. FC Saarbrücken | - | SV Weisenau | 2:0 | |
| 15:30 | 1. FSV Mainz 05 | - | Germania Metternich | 2:0 | ||
| 15:30 | FK Pirmasens | - | TuS Neuendorf | 1:1 | ||
| 15:30 | SV Alsenborn | - | VfR Frankenthal | 3:0 | ||
| 15:30 | Saar 05 Saarbrücken | - | Borussia Neunkirchen | 0:1 | ||
| 15:30 | FC 08 Homburg | - | SV Röchling Völklingen | 3:0 | ||
| 15:30 | Wormatia Worms | - | SV Südwest Ludwigshafen | 1:1 | ||
| 15:30 | Phönix Bellheim | - | Eintracht Trier | 1:2 |
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
1. FSV Mainz 05 | 6 | 5 | 1 | 0 | 13:3 | 10 | 11:1 |
| 2 |
|
Borussia Neunkirchen | 6 | 4 | 2 | 0 | 19:4 | 15 | 10:2 |
| 3 |
|
1. FC Saarbrücken | 6 | 5 | 0 | 1 | 16:3 | 13 | 10:2 |
| 4 |
|
FK Pirmasens | 6 | 3 | 2 | 1 | 14:6 | 8 | 8:4 |
| 5 |
|
Saar 05 Saarbrücken | 6 | 3 | 2 | 1 | 11:7 | 4 | 8:4 |
| 6 |
|
Eintracht Trier | 6 | 3 | 1 | 2 | 10:10 | 0 | 7:5 |
| 7 |
|
VfR Frankenthal | 6 | 2 | 2 | 2 | 11:10 | 1 | 6:6 |
| 8 |
|
SV Alsenborn | 6 | 3 | 0 | 3 | 12:12 | 0 | 6:6 |
| 9 |
|
SV Südwest Ludwigshafen | 6 | 2 | 1 | 3 | 11:12 | -1 | 5:7 |
| 10 |
|
Wormatia Worms | 6 | 1 | 3 | 2 | 9:11 | -2 | 5:7 |
| 11 |
|
SV Weisenau | 6 | 2 | 1 | 3 | 8:12 | -4 | 5:7 |
| 12 |
|
FC 08 Homburg | 6 | 1 | 3 | 2 | 7:13 | -6 | 5:7 |
| 13 |
|
Phönix Bellheim | 6 | 1 | 1 | 4 | 8:15 | -7 | 3:9 |
| 14 |
|
SV Röchling Völklingen | 6 | 1 | 1 | 4 | 3:12 | -9 | 3:9 |
| 15 |
|
TuS Neuendorf | 6 | 1 | 1 | 4 | 6:17 | -11 | 3:9 |
| 16 |
|
Germania Metternich | 6 | 0 | 1 | 5 | 1:12 | -11 | 1:11 |
