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| 28.08.1966 | 15:30 | 1. FC Saarbrücken | - | SV Südwest Ludwigshafen | 3:0 | |
| 15:30 | 1. FSV Mainz 05 | - | Eintracht Trier | 3:1 | ||
| 15:30 | FK Pirmasens | - | SV Weisenau | 6:0 | ||
| 15:30 | SV Alsenborn | - | Germania Metternich | 4:0 | ||
| 15:30 | Saar 05 Saarbrücken | - | TuS Neuendorf | 2:0 | ||
| 15:30 | VfR Frankenthal | - | Borussia Neunkirchen | 0:0 | ||
| 15:30 | Wormatia Worms | - | FC 08 Homburg | 2:2 | ||
| 15:30 | Phönix Bellheim | - | SV Röchling Völklingen | 4:1 |
| # | Mannschaft | Sp. | S. | U. | N. | Tore | Dif. | Pk. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
1. FC Saarbrücken | 4 | 4 | 0 | 0 | 13:1 | 12 | 8:0 |
| 2 |
|
1. FSV Mainz 05 | 4 | 4 | 0 | 0 | 10:2 | 8 | 8:0 |
| 3 |
|
Borussia Neunkirchen | 4 | 3 | 1 | 0 | 17:3 | 14 | 7:1 |
| 4 |
|
Saar 05 Saarbrücken | 4 | 3 | 1 | 0 | 7:2 | 5 | 7:1 |
| 5 |
|
FK Pirmasens | 4 | 2 | 1 | 1 | 12:5 | 7 | 5:3 |
| 6 |
|
VfR Frankenthal | 4 | 2 | 1 | 1 | 7:3 | 4 | 5:3 |
| 7 |
|
SV Weisenau | 4 | 2 | 0 | 2 | 7:9 | -2 | 4:4 |
| 8 |
|
Wormatia Worms | 4 | 1 | 1 | 2 | 7:9 | -2 | 3:5 |
| 9 |
|
Eintracht Trier | 4 | 1 | 1 | 2 | 6:8 | -2 | 3:5 |
| 10 |
|
Phönix Bellheim | 4 | 1 | 1 | 2 | 6:10 | -4 | 3:5 |
| 11 |
|
SV Südwest Ludwigshafen | 4 | 1 | 0 | 3 | 7:10 | -3 | 2:6 |
| 12 |
|
SV Alsenborn | 4 | 1 | 0 | 3 | 6:10 | -4 | 2:6 |
| 13 |
|
SV Röchling Völklingen | 4 | 1 | 0 | 3 | 2:8 | -6 | 2:6 |
| 14 |
|
FC 08 Homburg | 4 | 0 | 2 | 2 | 3:12 | -9 | 2:6 |
| 15 |
|
TuS Neuendorf | 4 | 1 | 0 | 3 | 3:13 | -10 | 2:6 |
| 16 |
|
Germania Metternich | 4 | 0 | 1 | 3 | 1:9 | -8 | 1:7 |
