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| H | River Plate | - | Boca Juniors | 2:1 (1:1) | ||
| R | Boca Juniors | - | River Plate | 3:0 (0:0) | ||
| H: 17.05.2000 | R: 24.05.2000 | Sieger: Boca Juniors | ||||
| H | CF América | - | Bolívar | 2:0 (0:0) | ||
| R | Bolívar | - | CF América | 1:2 (0:1) | ||
| H: 17.05.2000 | R: 25.05.2000 | Sieger: CF América | ||||
| H | Atlético Mineiro | - | Corinthians SP | 1:1 (0:1) | ||
| R | Corinthians SP | - | Atlético Mineiro | 2:1 (2:0) | ||
| H: 18.05.2000 | R: 23.05.2000 | Sieger: Corinthians SP | ||||
| H | Atlas Guadalajara | - | Palmeiras | 0:2 (0:1) | ||
| R | Palmeiras | - | Atlas Guadalajara | 3:2 (1:1) | ||
| H: 18.05.2000 | R: 25.05.2000 | Sieger: Palmeiras | ||||
