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| H | CD Mirandés | - | Athletic Club | 1:2 (0:2) | ||
| R | Athletic Club | - | CD Mirandés | 6:2 (3:0) | ||
| H: 31.01.2012 22:00 | R: 07.02.2012 22:00 | Sieger: Athletic Club | ||||
| H | Valencia CF | - | FC Barcelona | 1:1 (1:1) | ||
| R | FC Barcelona | - | Valencia CF | 2:0 (1:0) | ||
| H: 01.02.2012 21:00 | R: 08.02.2012 21:00 | Sieger: FC Barcelona | ||||
