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| H | Athletic Bilbao | - | FC Barcelona | 0:0 (0:0) | ||
| R | FC Barcelona | - | Athletic Bilbao | 0:1 (0:1) | ||
| H: 10.05.2023 18:00 | R: 14.05.2023 16:00 | Sieger: Athletic Bilbao | ||||
| H | Valencia CF | - | Real Betis | 1:3 (1:2) | ||
| R | Real Betis | - | Valencia CF | 1:2 (0:2) | ||
| H: 10.05.2023 19:30 | R: 14.05.2023 19:00 | Sieger: Real Betis | ||||
| H | Atlético Madrid | - | Real Madrid | 0:2 (0:1) | ||
| R | Real Madrid | - | Atlético Madrid | 2:2 (0:2, 0:2) n.V. | ||
| H: 10.05.2023 19:30 | R: 14.05.2023 16:00 | Sieger: Real Madrid | ||||
| H | UD Las Palmas | - | RC Celta | 5:0 (2:0) | ||
| R | RC Celta | - | UD Las Palmas | 3:4 (0:2) | ||
| H: 10.05.2023 20:00 | R: 14.05.2023 11:00 | Sieger: UD Las Palmas | ||||
