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| H | Manchester City | - | Atlético Madrid | 1:0 (0:0) | ||
| R | Atlético Madrid | - | Manchester City | 0:0 (0:0) | ||
| H: 05.04.2022 21:00 | R: 13.04.2022 21:00 | Sieger: Manchester City | ||||
| H | SL Benfica | - | Liverpool FC | 1:3 (0:2) | ||
| R | Liverpool FC | - | SL Benfica | 3:3 (1:1) | ||
| H: 05.04.2022 21:00 | R: 13.04.2022 21:00 | Sieger: Liverpool FC | ||||
| H | Chelsea FC | - | Real Madrid | 1:3 (1:2) | ||
| R | Real Madrid | - | Chelsea FC | 2:3 (0:1, 1:3) n.V. | ||
| H: 06.04.2022 21:00 | R: 12.04.2022 21:00 | Sieger: Real Madrid | ||||
| H | Villarreal CF | - | Bayern München | 1:0 (1:0) | ||
| R | Bayern München | - | Villarreal CF | 1:1 (0:0) | ||
| H: 06.04.2022 21:00 | R: 12.04.2022 21:00 | Sieger: Villarreal CF | ||||
